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Table 1 Material constants and kinetic parameters used in the simulation [15]

From: Role of reaction kinetics and mass transport in glucose sensing with nanopillar array electrodes

Parameter

 

Value

k 0

Standard rate constant

1.5 × 10-3 (m/s)

ε B

Association factor

2.6

α

Charge transfer coefficient

0.5

T

Absolute temperature

298 (K)

μ

Viscosity

1.1 (cP)

V A

Molar volume

0.1176 (m3/mol)

r p

Pore radius

200 × 10-9 (m)

L

Pore length

5 × 10-6 (m)

k

Surface reaction rate constant

5 × 10-4, 5 × 10-5, 5 × 10-7 (m/s)

M B

Molecular weight of water

18

R

Gas constant

8.31 (J/K. mol)

F

Faraday constant

9.648 × 104 (C/mol)

D F

Diffusivity of ferro- and ferri-cyanide

8 ×10-10m2/s